Chemistry S and P - Block Elements (S - Block Elements Not In Syllabus ) Physical and Chemical Properties of Group 17th Elements Single Correct MCQ
Published on: August 14, 2026

Which of the following trihalide are hydrolysed by nucleophilic attack of water ?

(1) BF 3 (2) NF 3 (3) PCl 3 (4) AsCl 3

A
Only 1
B
Only 2
C
Both (3) and (4)
D
Both (1) and (3)

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Text Solution

Verified by Experts
The correct answer is:
C

BF 3 is not hydrolysed due to p π – p π bonding bond strength of B – F bond increases. NF 3 is not hydrolysed because nitrogen do not have vacant d-orbitals. PCl 3 and AsCl 3 are easily hydrolysed because water molecules are able to coordinate with vacant d orbitals present in them.

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